Processing of a Titanomagnetite Concentrate by Sorption …

The size of the titanomagnetite concentrate particles did not exceed 0.07 mm. On the assumption that iron would be sorbed in the form of the Fe 3+ cation and titanium would be sorbed as the TiO 2+ cation, 1000 g titanomagnetite concentrate contains 40 g-equiv cations.. A single phase, Fe(Fe 1.173 Ti 0.54)O 4, was revealed by …

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Magnetic characterization of synthetic titanomagnetites: Quantifying

[1] A series of four synthetic basalts comprising titanomagnetite (Fe 3-x Ti x O 4) grains of varied size and titanium content have been produced by a glass-ceramic methodplementary characterization techniques of X-ray diffractometry, secondary electron microscopy, and transmission electron microscopy (TEM) demonstrate the …

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High-Pressure and High-Temperature Phase Transitions in Fe

Titanomagnetite (Fe 3– x Ti x O 4), one of the important magnetic minerals in igneous and metamorphic rocks, is a solid solution between Fe 3 O 4 magnetite (x = 0) and Fe 2 TiO 4 ulvöspinel (x = 1), formed by replacement of Fe 3+ by Ti 4+.Fe 2 TiO 4 ulvöspinel has an inverse spinel structure where tetrahedral sites are occupied by Fe 2+ …

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Magnetic Domain States and Critical Sizes in the Titanomagnetite …

The magnetic properties of the titanomagnetite series are known to vary strongly with composition, which may influence the domain states present in these minerals, and therefore the magnetic stability of the samples bearing them. We present results from micromagnetic simulations of titanomagnetite ellipsoids of varying shape and …

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Provenance of titanomagnetite in ironsands on the west …

Titanomagnetite ironsand occurs along the west coast of the North Island, New Zealand (Fig. 1), both onshore and offshore (Kear, 1965, Kear, 1979, Christie and Brathwaite, 1997, Carter, 1980).Mining of ironsand deposits at Waikato North Head (WNH), Taharoa and Waipipi since 1969 has produced magnetite concentrate for local steel …

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New soft chemistry route to titanomagnetite magnetic nanoparticles …

The Fe 2.5 Ti 0.5 O 4-DES nanoparticles had heterogeneous chemical composition with Ti-enriched core and Fe-enriched shell, and exhibited enhanced activity in catalytic decomposition of H 2 O 2 and oxidative degradation of organic contaminants at circumneutral pH values and room temperature due to the increased amount of ferrous …

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Calculation of diffusion coefficient and activation energy …

This transformation process is controlled by the diffusion rate of titanium, iron and oxygen ions in titanomagnetite. Electron microprobe studies of CREER and PETERSEN (1969) seem to indicate that in titanomagnetites Ti has a greater mobility than Fe. This is in accordance with theoretical considera- tions of FROLICH and STILLER …

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Magnetic properties of titanomagnetites and …

A chapter from a book on rock and mineral magnetism, covering the intrinsic and extrinsic properties of titanomagnetites and titanomaghemites, and their applications in …

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Relationship between the Texture and Composition of Titanomagnetite …

The nucleation and growth of crystals in igneous rocks is usually thought to occur under thermodynamic equilibrium conditions. However, recent studies on igneous textures and mineral compositions have shown that these processes probably occur under thermodynamic disequilibrium conditions. Titanomagnetite with variable crystal sizes …

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Process Mineralogy of Vanadium Titanomagnetite Ore in …

Vanadium titanomagnetite (VTM) is a valuable multi-element symbiotic ore mainly composed of iron, vanadium, and titanium, as well as small amounts of chromium, nickel and cobalt [1,2,3].The global resource reserves of the VTM ore are extremely rich (over 40 billion tons) and are mainly distributed in Russia, South Africa, China, the …

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Solid-Phase Transformations of Titanomagnetite and Ilmenite …

Abstract— The experimental works of Russian and foreign researchers focused on the behavior of ore minerals, such as titanomagnetite and ilmenite in an oxidizing environment in different temperature ranges, have been analyzed. The optimum temperature conditions and time interval for oxidizing roasting of mineral aggregates …

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Magnetite

Magnetite (Fe 3 O 4) is a common iron oxide mineral.It is a member of the spinel group. These are minerals that share the same structure but differ in chemical composition. Other notable members of the group are chromite and spinel.Magnetite is among the two major sources of iron.

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Process Mineralogical Analysis of a Typical Vanadium Titano …

The phase composition of VTM consists of 84.11% titanomagnetite, 6.52% hematite-limonite, 1.41% ilmenite, 3.87% olivine, and 3.31% alumina. The ore of VTM consists of individual metallic mineral grains and intergrowth grains with diverse structures and particle sizes. Titanomagnetite is predominantly found in self-formed grain structures.

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7 Magnetic properties of titanomagnetites and …

Low-temperature magnetic behavior in multidomain titanomagnetites is the result of the magnetic effects associated with isotropic points for x <0.4, rapid changes in …

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Raman Spectroscopy of Natural Titanomagnetites

titanomagnetite. In this study, Raman spectral patterns from natural titanomagnetite i.e., magnetite-ulvöspinel solid solution samples were analyzed to determine behavior of …

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Raman Spectroscopy of Natural Titanomagnetites

Titanomagnetite i.e., magnetite-ulvöspinel solid solution is a common Fe-Ti oxide mineral species that occurs naturally in igneous and metamorphic rocks [4,5], and as detrital material in ... lattice energy Fe2+ along with excess Fe3+ ions are relegated to the octahedral site [15]. However, in titanomagnetites, Fe3+ in the

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Effects of titanomagnetite reordering processes on thermal

The homogeneous titanomagnetite has been shown to undergo significant reordering at temperatures between ∼300 and 500°C, while the oxyexsolved …

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(IUCr) Site occupancy of Fe2+, Fe3+ and Ti4+ in titanomagnetite …

3. Absorption spectra and chemical shift. To conduct a preliminarily examination of the valence state of Fe ions in titanomagnetite, X-ray absorption near-edge structure (XANES) spectra were measured at the Fe K absorption edges at room temperature. Fig. 2 shows the XANES spectra of titanomagnetite, iron metal foil, FeO (NaCl structure), Fe …

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TITANOMAGNETITE PROPERTIES AND MICROSTRUCTURES

Ulvospinel (Fe2TiO4) and titanomagnetites (TM) (pseudo-binary (1-x)Fe3O4xFe2TiO4 system, where, e. g. TM95 corresponds to x = 0.95) were made using a solid-state synthesis technique. For single phase titanomagnetites (x>0.75), our measured lattice constants extends the previous work of Wechesler to Ti-rich solid solutions, and …

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Progressive Dissolution of Titanomagnetite in …

1 Introduction. High-resolution magnetic surveys have revealed that high-temperature hydrothermal up-flow zones hosted in basaltic ocean crust often lead to negative magnetic anomalies (Tivey & Dyment, 2010).The primary cause is attributed to hydrothermal alteration during fluid-rock reactions (Tivey & Johnson, 2002), in addition …

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Magnetic Properties of Oxidized (Cation-Deficient

A comprehensive study of the magnetic properties of nonstoichiometric (cation-deficient) titanomagnetites is described. Measurement of the saturation magnetization of synthetic samples provides information about the mechanism by which increasingly nonstoichiometric states evolve. It is concluded that in the spinel structure the inherent availability for …

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The extraction of vanadium from titanomagnetites and other sources

This process starts with an alkaline sodium orthovanadate solution at pH 13.7. Sodium ions migrate through the membrane, leaving vanadate ions on the anodic side (Fig. 11). As hydrogen ions are produced at the anode through the oxidation of water, the pH eventually decreases to 1.8, at which point vanadium can be recovered as NaHV …

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Titanomagnetite Properties and Microstructures

The first step in the investigation of the hypothesized role of titanomagnetite minerals in the large magnetic field anomalies on Mars is to determine synthetic routes to make single phase solid ...

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Inferred time- and temperature-dependent cation …

Intermediate composition titanomagnetites (0oxo1) are complex spinels, with three different metal cations and valence states (Fe2þ,Fe3þand Ti4þ), and significant work has been …

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Effects of titanomagnetite reordering processes on …

Titanomagnetite (Fe 3-x Ti x O 4, 0 ≤ x ≤ 1) is a common, naturally occurring magnetic mineral critical to many paleomagnetic studies. Underlying most interpretations is the assumption that, lacking chemical alteration, Curie temperature (T c) remains constant.However, recent work has demonstrated that T c of many natural …

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Using titanomagnetite textures to elucidate volcanic …

Titanomagnetite in andesitic magmas is especially sensitive to changes in temperature and oxygen fugacity immediately prior to and during eruptions. Two end-member eruption states can be distinguished by examining titanomagnetite textures in erupted rocks. Slow-ascent eruptions—characterized by near-stagnant magma bodies and slow effusion of ...

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Precise determination of major and trace elements in …

the magnetite.1,5 Titanomagnetite and the intergrowth of ilmenite lamellae within magnetite have been extensively investigated, owing to theirwidespread distribution in different

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Synthesis and properties of titanomagnetite (Fe3−xTixO4) …

Titanomagnetite (Fe 3− x Ti x O 4) nanoparticles were synthesized by room temperature aqueous precipitation, in which Ti(IV) replaces Fe(III) and is charge compensated by conversion of Fe(III) to Fe(II) in the unit cell.A comprehensive suite of tools was used to probe composition, structure, and magnetic properties down to site …

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Variable Ti-content and grain size of titanomagnetite as a …

Grains with bright contrast are titanomagnetite. Mt, titanomagnetite; Pl, plagioclase; Cpx, clinopyroxene; Gl, interstitial glass. Download : Download full-size image; Fig. 2. Variation of titanomagnetite grain size and magnetic properties with depth from the glassy margin of New Flow, with sub-sample labels as indicated at the bottom.

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Stratigraphy, provenance and localisation of the titanomagnetite …

Heavy mineral blacksands (titanomagnetite-rich ironsands) are contained within Pleistocene–Holocene dune and beach sands over 480 km along the west coast of the North Island (Fig. 1).The Pleistocene–Holocene sand sequences occur along, and offshore, of the current shoreline, and also within a series of coastal terraces parallel to …

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Fungal hyphae develop where titanomagnetite inclusions …

Nutrient foraging by fungi weathers rocks by mechanical and biochemical processes. Distinguishing fungal-driven transformation from abiotic mechanisms in soil remains a challenge due to ...

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Sustainable Selective Recovery of Sulfuric Acid and …

vanadium−titanomagnetite by leaching with concentrated sulfuric acid and hydrolysis precipitation.1−3 The waste acid of 5−6 m3 with a concentration of 20% and the acid wastewater of 50−80 m3 with a concentration of 2%−6% would be discharged per ton of titanium dioxide.4 TDWA also contains metal ions such as iron, vanadium, titanium and

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Ironsand (Titanomagnetite-Titanohematite): Chemistry, Magnetic

The Raman spectral patterns of analyzed natural titanomagnetite samples revealed peaks at 670-680 cm⁻¹, 544-603 cm⁻¹, 407-495 cm⁻¹ and 373-392 cm⁻¹ that correspond to the A1g, T2g (2 ...

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Magnetic properties of titanomagnetites and …

Magnetic properties of titanomagnetites and titanomaghemites. Chapters 3 to 6 have been largely concerned with models for the magnetic behaviour of materials. Chapter 3 dealt …

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Geophysical exploration of titanomagnetite ore deposits by geomagnetic

Geophysical techniques, such as magnetic and geoelectric ones, are useful for ore deposit exploration, represented by titanomagnetite. Titanomagnetite is a mineral composed of oxides of titanium and iron. Forty-seven magnetic profiles have been measured using two proton magnetometers to cover the study area with a direction …

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